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2,4,6-Triaminopyrimidine is an interesting and challenging molecule due to the presence of multiple hydrogen-bond donors and acceptors. Its noncovalent interactions with a variety of carboxylic acids provide several supramolecular aggregates with frequently occurring molecular synthons. The present work focuses on the supramolecular interactions of 2,4,6-triaminopyrimidinium 3-(indol-3-yl)propionate–3-(indol-3-yl)propionic acid (1/1), C₄H₈N₅⁺·C₁₁H₁₀NO₂⁻·C₁₁H₁₁NO₂, (I), 2,4,6-triaminopyrimidinium 2-(indol-3-yl)acetate, C₄H₈N₅⁺·C₁₀H₈NO₂⁻, (II), 2,4,6-triaminopyrimidinium 5-bromothiophene-2-carboxylate, C₄H₈N₅⁺·C₅H₂BrO₂S⁻, (III), and 2,4,6-triaminopyrimidinium 5-chlorothiophene-2-carboxylate, C₄H₈N₅⁺·C₅H₂ClO₂S⁻, (IV). All four salts exhibit robust homomeric and heteromericR₂²(8) ring motifs. Salts (I) and (II) develop sextuple [in (I)] and quadruple [in (I) and (II)] hydrogen-bonded arrays through fused-ring motifs. Salt (II) exhibits a rosette-like architecture. Salt (IV) is isostructural and isomorphous with salt (III), exhibiting an identical crystal structure with a different composition and an identical supramolecular architecture. In salts (III) and (IV), a linear hetero-tetrameric motif is formed and, in addition, both salts exhibit halogen–π interactions which enhance the crystal stability. All four salts develop a supramolecular hydrogen-bonded pattern facilitated by several N—H...O and N—H...N hydrogen bonds with multiple furcated donors and acceptors. 

In a quest to understand bio-inspired interactions of SO₂with hosts, we have observed the lone pair⋯π interaction between the aromatic ring and O of SO₂(3.11 Å), in addition to the interaction between S of SO₂and metal-bound thiolate (2.63 Å). 

The title compound, C 18 H 17 N 3 O 3 S·C 2 H 6 OS, crystallizes in the monoclinic space group P 2 1 /c . In the crystal, C 1 1 (9) chains of C—H...O interactions are formed, propogating in the c -axis direction. The N—H hydrogen atom forms a strong hydrogen bond with the oxygen atom of a DMSO solvate molecule.